A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres     

Guillermo M. MUÑOZ CARO  Frans J. M. RIETMEIJER  Virginia SOUZA‐EGIPSY  Maria Pilar VALLES‐GONZÁLEZ 《Meteoritics & planetary science》2012,47(2):248-261

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.  相似文献   

GPS differential code biases determination: methodology and analysis   总被引：1，自引：1，他引：0  

Jaume Sanz  J. Miguel Juan  Adrià Rovira-Garcia  Guillermo González-Casado 《GPS Solutions》2017,21(4):1549-1561

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Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth     

Pedro Alonso‐Davila  Oliva L. Torres‐Rivera  Roberto Leyva‐Ramos  Raul Ocampo‐Perez 《洁净——土壤、空气、水》2012,40(1):45-53

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.  相似文献   

Sky luminance distribution in Pamplona (Spain) during the summer period     

J.L. Torres  M. de Blas  A. García  A. Gracia  A. de Francisco 《Journal of Atmospheric and Solar》2010,72(5-6):382-388

In this work the outdoor daylight conditions in Pamplona (South Europe) during the summer period have been studied. The selected sky type (from fifteen standards) at a given moment is the one exhibiting the lowest RMSD when comparing the theoretical and experimental luminance distributions in the sky hemisphere. Two year data of luminance distribution registered every 10 min in 145 positions of the sky hemisphere have been used for selecting the sky type. The most frequent sky type in Pamplona is V.5 (cloudless polluted with a broad solar corona), with an occurrence of 29.5%. This result coincides with the one observed in a previous study in Athens.Six types of sky (V.5, IV.4, III.4, III.3, V.4 y II.2) out of the fifteen standards become practically the 80% of all the studied ones. Regarding a possible use in daylight climate studies, the frequency of occurrence of the fifteen types of sky for fourteen solar elevation intervals has been included.  相似文献   

Residual Exchange Flows in Subtropical Estuaries   总被引：1，自引：0，他引：1  

Arnoldo Valle-Levinson  Guillermo Gutierrez de Velasco  Armando Trasviña  Alejandro J. Souza  Reginaldo Durazo  Ashish J. Mehta 《Estuaries and Coasts》2009,32(1):54-67

Observations of residual exchange flows at the entrance to four subtropical estuaries, two of them semiarid, indicate that these flows are mainly tidally driven, as they compare favorably with theoretical patterns of tidal residual flows. In every estuary examined, the tidal behavior was that of a standing or near-standing wave, i.e., tidal elevation and tidal currents were nearly in quadrature. The pattern of exchange flow that persisted at every estuary exhibited inflow in the channel and outflow over the shoals. Curiously, but also fortuitously, this pattern coincides with the exchange pattern driven by density gradients in other estuaries. The tidal stresses and the residual elevation slopes should be the dominant mechanisms that drive such tidal residual pattern because the Stokes transport mechanism is negligible for standing or near-standing waves. Time series measurements from the semiarid estuaries showed fortnightly modulation of the residual flow by tidal forcing in such a way that the strongest net exchange flows developed with the largest tidal distortions, i.e., during spring tides. This modulation is opposite to the modulation that typically results in temperate estuaries, where the strongest net exchange flows tend to develop during neap tides. The fortnightly modulation on tidal residual currents could be inferred from previous theoretical results because residual currents arise from tidal distortions but is made explicit in this study. The findings advanced herein should allow the drawing of generalities about exchange flow patterns in subtropical estuaries where residual flows are mainly driven by tides.  相似文献   

Undocumented Students’ Narratives of Liminal Citizenship: High Aspirations,Exclusion, and “In-Between” Identities     

Rebecca Maria Torres  Melissa Wicks-Asbun 《The Professional geographer》2013,65(2):195-204

This study illustrates how national immigration policy relegates undocumented immigrant children to spaces of liminal citizenship, which shape their aspirations for higher education. Recognizing the power of migrant narratives, and the importance of privileging youths’ voices through children's geographies, we present the narratives of undocumented high school students from several rural North Carolina communities. Despite various barriers facing undocumented students, most have high academic aspirations. Students construct new forms of citizenship, legitimating their claims to higher education access through their achievement. Their liminal status, however, contributes to the formation of conflicted, “in-between” identities.  相似文献   

Nitrate to silicate ratio variability and the composition of micro-phytoplankton blooms in the inner-fjord of Seno Ballena (Strait of Magellan, 54°S)     

Rodrigo Torres  Máximo Frangópulos  Madeleine Hamamé  Vivian Montecino  Constanza Maureira  Gemita Pizarro  Brian Reid  Arnoldo Valle-Levinson  Jose Luis Blanco 《Continental Shelf Research》2011,31(3-4):244-253

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Paleosol geochemistry of the late Paleocene Goler Formation of Southern California     

Mark Torres  Robert Gaines 《Applied Geochemistry》2011

Paleosol (fossilized soil) geochemistry can provide a record of paleoclimatic conditions due to the relationships between pedogenic processes and climate. In this study, paleosols from the late Paleocene Goler Formation of Southern California were used to determine the paleoclimatic conditions active during pedogenesis. The enrichment and retention of soluble elements (Ca, Mg and Na) and the mobilization of Fe and Mn within the paleosol profiles suggest a climate with strongly seasonal precipitation. Similarly, variations in the Mn content and δ¹³C ratio of pedogenic carbonate nodules also reflect seasonal precipitation. Regional paleotopography was likely an important control on the paleoclimate of the Goler Formation due to rain shadow effects. Although the size and location of these ancient mountains are poorly constrained, the identification of climatic effects specifically associated with these variables provides new constraints.  相似文献   

The California Current System in relation to the Northeast Pacific Ocean circulation     

Guillermo Auad  Dean Roemmich  John Gilson 《Progress in Oceanography》2011,91(4):576-592

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Water relations and hydraulic architecture of two Patagonian steppe shrubs: Effect of slope orientation and microclimate     

Patricia A. Iogna  Sandra J. Bucci  Fabián G. Scholz  Guillermo Goldstein 《Journal of Arid Environments》2011,75(9):763-772

On a local scale, topography influences microclimate, vegetation structure and the morpho-physiological attributes of plants. We studied the effects of microclimatic differences between NE- and SW-facing slopes on the water relations and hydraulic properties of two dominant shrubs of the Patagonian steppe in Argentina (Retanilla patagonica and Colliguaja integerrima). The NE-facing slope had higher irradiance and air saturation deficits and lower soil water availability and wind speed than the SW-facing slope. Predawn and midday Ψ_L and osmotic potentials were significantly lower in shrubs on the NE-facing slope. Osmotic adjustment and more elastic cell walls helped the plants to cope with a more xeric environment on NE-facing slope. Higher water deficits on NE-facing slope were partially compensated by a higher leaf and stem water storage. While stem hydraulic efficiency did not vary between slopes, leaf hydraulic conductance was between 40% and 300% higher on the NE-facing slope. Changes observed in leaf size and in SLA were consistent with responses to mechanical forces of wind (smaller and scleromorphic leaves on SW-facing slope). Morpho-physiological adjustments observed at a short spatial scale allow maintenance of midday Ψ_L above the turgor loss point and demonstrate that leaves are more responsive to microclimatic selective pressures than stems.  相似文献